Keep an eye on the weather outside. Weather conditions can create many opportunities to improve or destroy a great picture. You can still get some great outdoor shots on a cloudy day. Compose your photos so that the gray sky is not actually in the frame. Don't let it stop you from taking great pictures.
Do not stop taking outdoor shots when the sun begins to set. There are many opportunities to keep going, especially if you have a tripod available to use with your camera. This piece of equipment allows for great low-light shots no matter if the sun is up or not.
When aiming for the perfect shot, remember to keep sunlight in mind. Too little and you can't see the subject. Too much and one of two things happen. The first is that too much sunlight is directed into the camera's lens or on the subject and washes out the picture. The second is the person being photographed has to blink or close his eyes because of the massive amounts of sunlight coming into his eyes.
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